Appendix C1 - Tables - Utilities and Energy Management

TABLE C-1-1: STATIONS MONITORED PER YEAR AND THEIR GEOGRAPHIC LOCATIONS

STATION	YEARS MONITORED	APPROXIMATE DEPTH		LATITUDE (N) ° ' "	LONGITUDE (W) ° ' "
STATION	YEARS MONITORED	(M)	(FT)	LATITUDE (N) ° ' "	LONGITUDE (W) ° ' "
P1	1994	3.2	10.5	42 28 00	76 30 30
P2	1994-1996	4.1	13.4	42 28 20	76 30 40
S1	1994	3.6	11.8	42 28 15	76 30 96
S2	1994	5.0	16.4	42 28 38	76 31 42
S3	1994	5.2	17.1	42 28 39	76 31 06
S4	1994	6.2	20.3	42 28 52	76 30 74
S5	1994	16.7	54.8	42 28 51	76 31 55
S6	1994	15.4	50.5	42 28 67	76 31 15
S7	1994	12.4	40.7	42 28 78	76 30 77
S8	1994	42.5	139.4	42 28 79	76 31 63
P3	1994	43.4	142.4	42 28 93	76 31 30
S9	1994	46.2	151.5	42 29 00	76 30 90
P4	1994-1996	65.3	214.2	42 29 31	76 31 41
S10	1994	68.5	224.7	42 29 42	76 31 90
S11	1994-1996	72.0	236.2	42 29 60	76 31 45
S12	1994	66.4	217.8	42 29 76	76 31 11
Reference (R1)	1994	100	328.0	42 32 40	76 33 68
Reference (R2)	1994	103	337.8	42 32 18	76 32 70

TABLE C-1-2: SUMMARY OF 1994 MONITORING PROGRAM BY ANALYTE, STATION, DEPTH, AND FREQUENCY

ANALYTE	STATIONS	DEPTHS	FREQUENCY DURATION
Temperature Dissolved Oxygen pH Total Dissolved Solids Specific Conductance Oxidation/Reduction Potential Secchi Disk Transparency	P1 - P4 S1 - S12 R1 - R2	2 - 5 meter intervals (shallow) 10 meter intervals (deep)	Weekly (June - September) Monthly (October - December)
Ammonia-Nitrogen Total Phosphorus Soluble Reactive Phosphorus Silica Nitrate-Nitrogen Turbidity	P1 - P4	P1 and P2: surface, bottom P3 and P4: 10 meter intervals	Biweekly (June - September) Monthly (October - December)
5-Day BOD Total Organic Carbon Total Suspended Solids Chloride	P1 - P4	P1 and P2: surface, bottom P3 and P4: 10 meter intervals	Monthly (June - December)
Chlorophyll a Phaeophytin	P1 - P4 R1, R2	P1 and P2: surface, bottom P3, P4, R1, and R2: 10 meter intervals	Biweekly (June - September) Monthly (October - December)
Phytoplankton	P1 - P4 R1, R2	Epilimnetic composites	P1 - P4 biweekly (June - September) R1, R2 monthly (July - September)
Zooplankton	P2, P4 R1, R2	Water column net haul	P1 - P4 biweekly (June - September) R1, R2 monthly (July - September)
Benthic Invertebrates	P1 - P4, R1, R2	Lake bottom sediments	Once (July 1994)
Dioxin (2,3,7,8-TCDD)	P4	60m	Once (November 1994)
Trihalomethane Formation Potential (THMFP) and Haloacetic Acid	P4	60m	Once (August 1994)

TABLE C-1-3: SUMMARY OF 1995 WATER QUALITY MONITORING PROGRAM BY ANALYTE, STATION, DEPTH, AND FREQUENCY

ANALYTE	STATIONS	DEPTHS	FREQUENCY, DURATION
Total P and SRP	P4, S11	10 m intervals (0, 10, 20, 30, 40, 50, 60, 70)	Monthly: April and May Biweekly: June-Nov
Total P and SRP	P2	Mid-depth sample (2 m)	Monthly: April and May Biweekly: June-Nov
Field Hydrolab Parameters (DO, pH, specific conductivity)	P4, S11	10 m intervals	Monthly: April and May Biweekly: June-Nov
Field Hydrolab Parameters (DO, pH, specific conductivity)	P2	1 m intervals	Monthly: April and May Biweekly: June-Nov
Zooplankton: Species Composition	P4, P2	Depth integrated (through water column)	3 samples: April-June
Phytoplankton: Species Composition	P4	Depth integrated (10 m)	3 samples: April-June
Phytoplankton: Species Composition	P2	Depth integrated (4 m)	3 samples: April-June
Chlorophyll a	P4, S11	Depth integrated (10 m)	Monthly: April and May Biweekly: June-Nov
Chlorophyll a	P2	Depth integrated (4 m)	Monthly: April and May Biweekly: June-Nov
Total Suspended Solids	S11	Every 10 m (0, 10, 20, 30, 40, 50, 60, 70)	Monthly: April and May Biweekly: June-Nov
Total Suspended Solids	P2	Mid-depth sample (2 m)	Monthly: April and May Biweekly: June-Nov
Turbidity	S11	Every 10 m	Monthly: April and May Biweekly: June-Nov
Turbidity	P2	Mid-depth sample (2 m)	Monthly: April and May Biweekly: June-Nov
Secchi disk	P4, S11, P2	Surface	Monthly: April and May Biweekly: June-Nov
Silica	S11	10 m intervals	Monthly: April and May Biweekly: June-Nov
Silica	P2	Mid-depth sample (2 m)	Monthly: April and May Biweekly: June-Nov

TABLE C-1-4: SUMMARY OF 1996 WATER QUALITY MONITORING PROGRAM BY ANALYTE, STATION, DEPTH, AND FREQUENCY

ANALYTE	STATIONS	DEPTHS	FREQUENCY, DURATION
Total P and SRP	P4, S11	10 m intervals (0, 10, 20, 30, 40, 50, 60, 70)	Monthly: April, May, Oct Biweekly: June-Sept
Total P and SRP	P2	Mid-depth sample (2m)	Monthly: April,May, Oct Biweekly: June-Sept
Field Hydrolab Parameters (DO, pH, specific conductivity)	P4, S11	10 m intervals	Monthly: April, May, Oct Biweekly: June-Sept
Field Hydrolab Parameters (DO, pH, specific conductivity)	P2	1m intervals	Monthly: April, May, Oct Biweekly: June-Sept
Phytoplankton: Species Composition	P2	Depth integrated (4 m)	Biweekly: April 24-Sept 18
Chlorophyll a	P4, S11	Depth integrated (10 m)	Monthly: April, May, Oct Biweekly: June-Sept
Chlorophyll a	P2	Depth integrated (4 m)
Total Suspended Solids	S11	Every 10 m (0, 10, 20, 30, 40, 50, 60, 70)	Monthly: April, May, Oct Biweekly: June-Sept
Total Suspended Solids	P2	Mid-depth sample (2 m)	Monthly: April, May, Oct Biweekly: June-Sept
Turbidity	S11	Every 10 m	Monthly: April, May, Oct Biweekly: June-Sept
Turbidity	P2	Mid-depth sample (2 m)	Monthly: April, May, Oct Biweekly: June-Sept
Secchi disk	P4, S11, P2	Surface	Monthly: April, May, Oct Biweekly: June-Sept

TABLE C-1-5: LABORATORY METHODS AND LIMITS OF DETECTION

ANALYTE	LABORATORY	METHOD	YEARS	LIMIT OF DETECTION (MG/L)
Chlorophyll a	LSL, Inc.	SM 17th 10200H	1994 - 1996	0.001, 0.0005
Total Phosphorus	LSL, Inc.	EPA 365.1	1994 - 1996	0.01 (1994) 0.002 (1995)
Total Phosphorus	IA	SM 16th C III	1995, 1996	0.0015
Soluble Reactive Phos.	IA	SM 16th 424F	1995, 1996	0.0015
Total Suspended Solids	LSL, Inc.	EPA 160.2	1994 - 1996	4, 1.0
Turbidity	LSL, Inc.	EPA 180.1	1994 - 1996	1
Silica	LSL, Inc.	EPA 370.1	1994	0.1, 0.02
Silica	LSL, Inc.	USGS I-2700-85	1995	4.0, 0.1
Ammonia as N	LSL, Inc.	EPA 350.1	1994	0.03, 0.1
BOD₅ Day	LSL, Inc.	EPA 405.1	1994	2.0, 4.0
Chloride	LSL, Inc.	SM 16th 407A	1994	N/A
Nitrate as N	LSL, Inc.	EPA 353.1	1994	N/A
Total Organic Carbon	LSL, Inc.	SM 17th 5310	1994	1
Phaeophytin	LSL, Inc.	SM 17th 10200H	1994	0.001

TABLE C-1-7: LIFE SCIENCE LABORATORY, INC. QA/QC PROGRAM

Automated Colorimetric Analyses Without Distillation or Digestion (Such as Ammonia, Nitrate, or Silica)

Prep. blanks	Frequency	N/A
	Specification	N/A
	Corrective Action	N/A
Matrix Spikes	Frequency	5%
	Specification		>Statistical control limits
	Corrective Action	None	Flag # for that sample only
Matrix Duplicates	Frequency	10%
	Specification		>Statistical limits
	Corrective Action	None	Flag # for that sample only
Standard Curve	Frequency	5 pts. with low standard at RDL	Standards preped daily	Matching of curves
	Specification	CC>/= 0.9970		Not allowed
	Corrective Action	Rerun standards and/or reprep. standards		N/A
ICB/CCB	Frequency	10% and at end
	Specification
	Corrective Action	Halt analysis and correct
ICV/CCV	Frequency	10% and at end
	Specification		>Statistical control limits
	Corrective Action	None	Halt analysis and fix problem

Manual Colorimetric Analyses With Distillation or Digestion (Such as Total Phosphate)

Prep. blanks	Frequency	5%
	Specification		>RDL and samples >10X blank conc.	>RDL and samples <10X blank conc.	>10X RDL
	Corrective Action	None	None	Flag #	Reprep. batch
Matrix Spikes	Frequency	5%
	Specification		>Statistical control limits
	Corrective Action	None	Flag # for that sample only
Matrix Duplicates	Frequency	10%
	Specification		>Statistical control limits
	Corrective Action	None	Flag # for that sample only
Blank Spikes	Frequency	5%
	Specification	80 - 120% R
	Corrective Action	Reprep. batch
LCS	Frequency	5% (only upon client request)
	Specification	80 - 120% R
	Corrective Action	Reprep. batch
Standard Curve	Frequency	5 pts. with low standard at RDL		If curve
	Specification	CC>/= 0.9995		2 standards at diff. conc. +/- 10% of orig.
	Corrective Action	Rerun standards and/or reprep. standards		or reprep. standards and rerun curve
ICB/CCB	Frequency	10% and at end
	Specification
	Corrective Action	Halt analysis and correct instrument
ICV/CCV	Frequency	10% and at end
	Specification		>Statistical control limits
	Corrective Action	None	Halt analysis and fix problem

Manual Colorimetric Analyses Without Distillation or Digestion (Such as Ortho-Phosphate)

Prep. blanks	Frequency	5%
	Specification		>RDL and samples >10X blank conc.	>RDL and samples <10X blank conc.	>10X RDL
	Corrective Action	None	None	Flag #	Reprep. batch
Matrix Spikes	Frequency	5%
	Specification		>Statistical control limits
	Corrective Action	None	Flag # for that sample only
Matrix Duplicates	Frequency	10%
	Specification		>Statistical control limits
	Corrective Action	None	Flag # for that sample only
Standard Curve	Frequency	5 pts. with low standard at RDL		If curve
Standard Curve	Specification	CC>/=0.9995		2 standards at diff. conc. =/>90%R
Standard Curve (continued)	Corrective Action	Rerun standards and/or reprep standards		or reprep. standards and run full curve
ICB/CCB	Frequency	10% and at end
	Specification
	Corrective Action	Halt analysis and correct instrument problem
ICV/CCV	Frequency	10% and at end
	Specification		>Statistical control limits
	Corrective Action	None	Halt analysis and fix problem

Gravimetric Techniques (Such as Total Suspended Solids)

Prep. blanks	Frequency	5%
	Specification
	Corrective Action	Rerun blank
Matrix Duplicates	Frequency	10%
	Specification		>Statistical control limits
	Corrective Action	None	Flag # for that sample only

Turbidity

Matrix Duplicates	Frequency	10%
	Specification		>Statistical control limits
	Corrective Action	None	Flag # for that sample only
Standard Curve	Frequency	Calibrate every 12 hours
	Specification	Within 10% of theoretical check value
	Corrective Action	Recalibrate

Chlorophyll and Phaeophytin Manual Colorimetric Analysis

Prep. blanks	Frequency	5%
	Specification		>RDL and samples > 10X blank conc.	>RDL and samples <10X blank conc.	>10X RDL
	Corrective Action	None	None	Flag #	Reprep. batch
Matrix Duplicates	Frequency	As provided by client
	Specification		>Statistical control limits
	Corrective Action	None	Flag # for that sample only

Notes: LCS = Lab Control Sample
RDL = Reportable Detection Limit
CC = Correlation Coefficient
ICB/CCB = Initial Calibration Blank/Continuing Calibration Blank
ICV/CCV = Initial Calibration Verification/Continuing Calibration Verification

Ranges of Standard Curves, 1994-1996
Orthophosphate (Soluble Reactive Phosphate)

DATA ANALYZED	LINEAR RANGE	NO. OF STANDARDS
6/16/94 - 6/30/94	0.04 mg/l - 2.00 mg/l	6 standards used
7/13/94	0.004 mg/l - 0.200 mg/l	6 standards used
7/28/94	0.010 mg/l - 0.100 mg/l	5 standards used
8/11/94 - 8/25/94	0.010 mg/l - 0.200 mg/l	6 standards used
9/8/94 - 9/23/94	0.010 mg/l - 0.100 mg/l	5 standards used
10/20/94 - 11/17/94	0.010 mg/l - 0.200 mg/l	6 standards used
12/23/94	0.010 mg/l - 0.100 mg/l	5 standards used
4/26/95 - 9/20/95	0.002 mg/l - 0.100 mg/l	6 standards used
10/24/95 - 10/25/95	0.002 mg/l - 0.050 mg/l	5 standards used

Total Phosphate

DATA ANALYZED	LINEAR RANGE	NO. OF STANDARDS
7/12/94	0.005 mg/l - 0.200 mg/l	7 standards used
7/22/94 - 9/22/94	0.010 mg/l - 0.200 mg/l	6 standards used
10/17/94	0.005 mg/l - 0.200 mg/l	7 standards used
10/21/94 - 12/8/94	0.010 mg/l - 0.200 mg/l	6 standards used
1/9/95	0.005 mg/l - 0.200 mg/l	7 standards used
5/3/95 - 9/6/95	0.002 mg/l - 0.100 mg/l	6 standards used
9/20/95 - 10/25/95	0.002 mg/l - 0.050 mg/l	5 standards used
4/29/96	0.002 mg/l - 0.100 mg/l	5 standards used
5/22/96 - 8/28/96	0.002 mg/l - 0.100 mg/l	6 standards used

Chlorophyll-a

DATA ANALYZED
6/14/94 - 8/8/96	In place of a standard curve, chlorophyll-a is quantitated using the trichromatic method listed in Standard Methods with a mathematical calculation utilizing the industry standard absorption coefficient for the compound.

Return to Table of Contents

BACK TO THE TOP